This contribution scrutinises how introducing a statutory minimum wage of EUR 8.50 per hour on January 1, 2015, impacted German employees’ decision towards a union membership. Based on representative data from the ‘Panel Labour Market and Social Security’, we apply a logistic difference-in-differences propensity score matching approach on entries in and withdrawals from unions in the German Trade Union Confederation (Deutscher Gewerkschaftsbund, DGB). Our results show no separate effect on withdrawals from or entries in unions by the minimum wage introduction for those employees who benefited financially from it, but a significant increase of entries overall. Thus, unions’ campaign for a minimum wage strengthened their position in total but did not reverse the segmentation of union membership patterns.